La Liga giants Real Madrid are reportedly interested in signing Virgil van Dijk from Liverpool - and they have also considered exchanging four stars, namely, Gareth Bale, Isco, Marco Asensio and Luka Modric, for the Dutch defender.
A statement released by the Dutch Football Association (KNVB) said Van Dijk's absence for the Estonia game was due to "personal circumstances".
Van Dijk captained Netherlands in their 0-0 draw with Northern Ireland on Saturday that secured qualification for next summer's European Championships.
The Dutch had missed the last European Championship finals in France, plus the World Cup in Russian Federation previous year.
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Van Dijk is the fifth Liverpool player who has withdrawn from global duty in the past week.
"National team coach Ronald Koeman can not rely on VirgiI van Dijk on Tuesday against Estonia", read a short statement from the Royal Dutch Football Association (KNVB).
At stake in Tuesday's game will be top spot in Group C which is now held by Germany who are two points ahead of the Dutch.
Meanwhile, Liverpool have got off to a stunning start in the Premier League, winning eleven out of the twelve matches they have played so far.