The officer fired three shots on Monday morning toward two black-clad protesters in a neighbourhood where traffic had been snarled by roadblocks, video footage from the scene shows.
Hong Kong police shot protesters on Monday in the latest escalation in the city's political crisis.
Police fired tear gas in the narrow streets of the Central business district where some protesters, crouching behind umbrellas, blocked streets as office workers crowded the pavements and hurled anti-government abuse.
The city's rail operator MTR Corp. said it had shut the Whampoa, Kwai Fong and Tung Chung subway stations amid widespread vandalism and disruptions.
The shooting is likely to inflame anger further in this semi-autonomous Chinese territory, after a student who fell during an earlier protest succumbed to his injuries on Friday and police arrested six pro-democracy lawmakers over the weekend. He grabbed a protester in white, and shot another black-clad protester in the stomach at close range.
However, in a statement Amnesty International Hong Kong said that "these are not policing measures - these are officers out of control with a mindset of retaliation".
The panel said in a statement that the existing Hong Kong police complaints process lacked "the powers, capacity and independent investigative capability necessary to match the scale of events and the standards required of an worldwide police watchdog operating in a society that values freedoms and rights". Police said the man was in critical condition, while offering few other details.
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But Harry and Meghan also wanted to show support for the families of service personnel who are now deployed overseas, it said. Meghan exclaims in the clip, before gesturing to the child's bottom gum and saying, " Archie just got two teeth".
Police said the motorcycling officer had been suspended. More than 3,300 people have been arrested in the protests. Police chased them away with pepper spray, hitting some bystanders as well.
Since early June, Hong Kong has been rocked by protests triggered by a bill that would have allowed the extradition of accused individuals to mainland China for trial.
Chief Executive Carrie Lam, in an evening news conference on Monday, condemned what she described as the violent attacks of "rioters", stressing that the government will not satisfy their "political demands". "Only in this way can Hong Kong have a better future", she said.
More than 1000 complaints about police operations during the protests have been received, including 95 allegations of assault and over 460 reports of misconduct.
The government invoked emergency powers to introduce the ban on face masks, which protesters have used to protect themselves from tear gas as well as to shield their identities.
I haven't seen the police propose concrete actions to show how they would address complaints from society. Students threw petrol bombs and broke windows.
Online messages circulated calling for people to gather at shopping malls around the city to mourn the death of Chow Tsz-lok, a 22-year-old student, who fell from a auto park floor in unexplained circumstances on November 4.
Police said in a statement radical protesters had set up barricades at multiple locations across the city and warned the demonstrators to "stop their illegal acts immediately". Hong Kong Polytechnic University said all classes before 2:30pm would be cancelled.