On Monday, nine Catalan separatist leaders were jailed for between nine and 13 years for their role in an illegal referendum and subsequent failed independence bid, sparking protests and clashes across the region.
Protesters have set cars on fire and threw petrol bombs at police in Barcelona on Wednesday, continuing the unrest sparked by the sentencing of the Catalan separatist leaders.
He said in a news conference on Thursday: "There has been a lot of chatter about that game".
"The actions we have been staging over the past few days testify to the helplessness we feel as the Spanish state continues to reject (independence) and threaten us, while Europe remains silent", a 23-year-old accountant, who would only give his first name as David, told AFP.
"We are experiencing episodes of great violence in Catalonia carried out by minority groups which are perfectly organised", he said, vowing there would be "no impunity" for those involved in the violence. The game is going to be played without problems. I don't know. a year ago we were talking about a possible game that we were going to play in the USA which didn't happen. We also played at the Wanda Metropolitano against Atletico Madrid [in 2017, after the Catalan independence referendum] and everyone said there would be drama and there was our fans, their fans - everyone has a right to express an opinion in the ground and we think the same thing will happen here.
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"It should be played under normal circumstances".
Amid a suggestion a decision on the fixture could be taken as early as this Thursday by league officials, Valverde was asked whether a postponement might most help Barca or Madrid.
"Making noise is the only way to make people pay attention to us", he said.
On the 11th matchday, the Catalans will host Real Valladolid on Tuesday, October 29, and Real Madrid will make the short trip to Leganes on Wednesday, October 30. "However, in these type of games that is not that important as players are always ready to play these games".
He added: "I would prefer to play it as would my players".