McClain admitted to accessing Worden's bank accounts while she was in space.
McClain told the daily through a lawyer that she was merely going through the couple's finances to make sure everything was in order.
McClain went to court in 2018 seeking shared parenting rights and the sole right to designate the residence of Worden's son, who was born about a year before the two met, the Times reported.
The New York Times noted that NASA caught a widow trying to sell a Moon rock in 2011, while an Austrian businessman sued a space tourism outfit in 2017 to reclaim his deposit on a trip that appeared to have stalled.
McClain had accessed the account throughout the relationship with Worden's full knowledge, Hardin said. "I knew it was not O.K.", Worden said.
Hardin said McClain has routinely checked the account and was never informed she could no longer access it.
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The couple were married in 2014. "I was shocked and appalled at the audacity by her to think that she could get away with that, and I was very disheartened that I couldn't keep anything private", she said.
McCain denied the allegations in a short statement on Twitter.
There are five worldwide space agencies involved in the ISS - the US, Canada, Japan, Russia and the European Space Agency - and their agreed legal frameworks stipulate that national law applies to any people and possessions in space, meaning Americans are subject to American law in space, and Russians subject to Russian law, etc.
Recent divorceGround personnel help NASA astronaut Anne McClain to get out of the Soyuz MS-11 capsule as she and the rest of the crew returned to earth in June this year.
Worden denied any wrongdoing and the case was dropped several months later.
Ms McClain, a decorated pilot, was a West Point graduate who flew more than 800 combat hours in Operation Iraqi Freedom before joining Nasa in 2013.
Mark Sundahl, director of the Global Space Law Center at Cleveland State University, said that he wasn't aware of any previous allegation of a crime committed in space, according to the Times.