The game kicks off at 1.05am United Kingdom time and is being held at the Hard Rock Stadium in Miami.
His negative disposition during the pre-season tour in the United States are a continuation of last season's public outbursts at his own players.
Mourinho who had been a downcast figure throughout the tour heaped praise on the attitude of his squad that was missing a number of key players due to the World Cup.
The Frenchman's relationship with his manager has been at breaking point and he hit back at Mourinho's jibes with a message on Twitter.
"In every pre-season, it happens the same, with every club, which is that the manager wants more".
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"The boys tried everything, they gave everything, they know we have to try to fight for the best result but tactically it means nothing".
Madrid got one back just before the break through Karim Benzema, who latched on to a probing cross by Theo Hernandez.
United doubled the lead nine minutes later after Darmian, Mata and Sanchez combined in a sensational team move to tee up Herrera, who fired a half-volley past Kiko Casilla approaching the half-hour mark.
United play Champions League holders Real Madrid and German champions Bayern Munich in their next two friendlies before hosting Leicester City in the opening league fixture on August 10. "The messages we are getting from the manager are positive ones and that is important for us going forward". It's possible. And that one I gave a list to my club five names a few months ago, and I wait to see if it's possible to have one of these players.
United's senior players, including £52 million summer signing Fred, Sanchez and Juan Mata were in one group, but their effort was minimal and passes were frequently intercepted or went astray. Back tomorrow (Thursday) in Manchester'.