June's four-team play-off will see England take on Netherlands in the semi-finals for the chance to face either Switzerland or hosts Portugal in a Porto final.
And the World Cup Golden Boot victor thinks he is "in the zone" in front of goal ahead of a massive three months for club and country with Spurs set to face Manchester City in the Champions League quarter-finals and in a battle for a top-four Premier League finish.
According to Kane, he said: "Our aim is to win the Nations League and we can do that if we are fully focused on our job". It is exciting. I have said before to have a chance to win a trophy in an England shirt is not very often. "If we have a good summer and win that trophy, in my eyes it's a better year".
"2018 was fantastic but the main thing for me is the team, trying to win things, and we have a chance this year".
A relative lack of expectations heading into the World Cup appeared a liberating factor for England, whose run in Russian Federation saw a fanbase re-establish affections with their national side.
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Gareth Southgate's squad are back together for the first time in 2019, with the Czechs their first test before a trip to Montenegro for the second qualifier on Monday.
"I think we feel that expectation where people now expect us to do well and I think before the World Cup there was no expectation".
"That was big for us, to prove that it wasn't just a one-off, that this team were really building for something special".
"Everyone handles expectation differently".
Chelsea turned down a number of bids for Hudson-Odoi from Bayern Munich during the January window, as well as rejecting a transfer request from the player himself, but they are braced for renewed interest this summer. "There will be one or two further cases in the future before we get to a solution".
England captain Harry Kane is excited by the promotion of under-21 worldwide Callum Hudson-Odoi to the senior squad.