Mike Pence, working to ramp up pressure for the ouster of Venezuelan President Nicolas Maduro, told a rally on Friday that the time for dialogue had ended and all options were on the table to replace Mr Maduro's government.
In an interview Thursday, Guaido told The Associated Press that the move will be a "new test" for Venezuela's military, whose top brass has sided with socialist President Nicolas Maduro since protests against his rule broke out last week.
The Vice President said: "We are prepared to work with the provisional government of Venezuela, the National Assembly and President Guaido".
In a country where the socialist leader's foes often end up behind bars, Guaido has thus far managed to avoid arrest, but in recent days authorities have let it be known that even as his powerful global support grows Guaido isn't untouchable.
Venezuela's Supreme Court - dominated by regime loyalists - have frozen his assets and ordered him not to leave the country.
Marquez also shared the details of his meeting with Vice President Pence this week and said the main focus was humanitarian aid for the Venezuelan people. The US on Thursday urged all European countries to recognize Guaido.
"That's what we were asking of them, to respect the Constitution and restore the constitutional order that has been ruptured for the last two years by the Maduro regime", he said.
Stillhart said that the ICRC now brings in its own medical supplies and emergency trauma care to support six hospitals located across the country. Yankee, hands off our oil industry!
Francisco Sucre heads the worldwide committee of the opposition-led National Assembly in Venezuela.
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The 35-year-old president of the National Assembly said he had a 20-month old daughter at home and would be holding FAES accountable for "whatever they do to my baby".
"The objective is obvious".
Guaido called the surprise visit "cowardly" and said it "crossed the red line".
Guaido said he was evaluating how to take control of state-run oil firm PDVSA's US unit Citgo, Venezuela's biggest foreign asset, as the Trump administration tries to use the company as leverage to topple Maduro.
Organization of American States chief Luis Almagro denounced the "intimidation" of Guaido.
The majority of other, smaller European Union countries will throw their support behind Guaido but have agreed to avoid explicitly using the words "recognition" and "recognize".
Guaidó is pressing forward with establishing a transitional government after swearing himself in as the nation's rightful president.
"The majority of those in service agree that the country's recent travails are untenable", he wrote. The previous day, a Boeing 757 owned by the Russian company Yerofei flew from Moscow to Caracas through Dubai, increasing speculation among journalists and anti-Maduro politicians that the jet was to remove $840 million, or 20 tons of gold, from Venezuela's national bank.
While most have left for other South American countries, thousands have made their way to southern Florida, joining migrants from Cuba and other parts of Latin America.