Llorente enjoyed a rise to prominence towards the end of 2018, starting their last three LaLiga games as well as Club World Cup wins over Kashima Antlers and Al Ain.
Cazorla has relaunched his injury-hit career back in Spain this season, returning to his homeland after a six-year stint with the Gunners that was cut short by a awful run of injuries.
Real calmly set about reversing their fortunes, however, and when Lucas Vazquez whipped in a teasing cross, Benzema buried his header to square up the match just three minutes later.
The former Arsenal midfielder bagged a brace - including an 82nd-minute equaliser - as Real slumped to an eighth league game without victory in just 17 games this term, leaving them seven points adrift of leaders Barcelona.
But they lost their grip on the game after Gareth Bale was substituted soon after the interval with a knock.
Villarreal eventually punished their opponents' wasteful finishing and fatigue as Santi Cazorla headed in at the back post after an excellent cross from Pablo Fornals, sending their home fans wild and travelling Real supporters towards the exit.
Solari was forced into a substitution at the beginning of the second stanza as Gareth Bale did not make his return from break due to injury and he as replaced by Isco.
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First Victor Ruiz headed high and wide from Cazorla's cross, then Alvaro Gonzalez followed suit.
"It could be said the result was fair".
The home side is battling against relegation, with Villarreal sitting at the top of the drop zone with 15 points through 16 matches.
"I have no updates to tell you about the matter", Solari said during a press conference ahead of Madrid's La Liga game against Villarreal, scheduled for Thursday, reports Efe news.
"We have to keep fighting always, and we will", Solari said, when asked about his team's title hopes.
"I imagine that every game from now on will be a battle, a war to survive but hopefully we'll come through it, and this point gives us a big emotional boost".