A statement from the Foreign Office said: "We are in contact with the Spanish authorities responding to flooding in Majorca, and urgently seeking updates from them".
Susan Guile and John Gray jetted out to the Balearic Islands on Sunday (7) for an 11-night holiday.
Two British tourists are among the five dead in the flash flood which hit the eastern part of the island overnight, according to reports this morning.
The Britons, who were married and in their seventies, were travelling by taxi about 40 miles east of the Spanish island's capital, Palma, when the auto was swept away.
Two of those killed were in Sant Llorenc, one in Arta and two more in S'Illot.
Spanish Prime Minister Pedro Sanchez tweeted his "solidarity and support for the relatives and friends of the victims, and for all those affected by this tragic flooding".
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Images posted on social media showed cars being swept along narrow streets by torrents of brown water.
Spanish authorities said 80 soldiers would join more than 100 rescuers working in the area.
A sports centre - the Miguel Ángel Nadal sports centre in the town of Manacor - has opened its doors to give shelter to local people whose homes have been damaged.
Spanish lawmakers observed a minute of silence in parliament in memory of the victims. The flooding also affected phone communications and forced the closure of at least seven major roads.
The agency's data showed that some parts of the island received up to 23 centimeters (nine inches) of rainfall in around four hours on Tuesday evening, more than one third of the average amount that rains annually.
In December 2016, there was widespread flooding in southern Spain and several people died.