"Actually I don't like to compare players but we had similar players and questions about Robbo (Andrew Robertson) and Alex Oxlade-Chamberlain", he said. "It's not going to help anyone".
And England global Kane has enjoyed facing Liverpool, having been directly involved in seven goals in seven Premier League appearances against them (five goals, two assists), including four in the last two.
"Alli is a bit unlucky, he suffered a small injury after 20 minutes against Spain", Pochettino told Sky Sports.
Vorm, 34, certainly isn't short of experience as he made 97 Premier League appearances for Swansea before moving to North London in 2014 and he has played against Liverpool on nine occasions during his career.
"The plan was - and is still - he will make us better and that is what we are working on".
"It's not that I want to justify him, it's only because the period during the season always change". Son played a more advanced role that day and Pochettino might be tempted to thrust him into the action this weekend in the hope of a repeat scenario. He's one of the best strikers in the world.
"That's why the expectations and perspective are completely different to another player". However, Dan Kilpatrick reports that Lloris will remain as club captain, despite speculation he could lose the armband.
"He said he is sorry and accepts his mistake", said Mauricio Pochettino.
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Asked if the World Cup victor would remain as captain, Pochettino said: "Of course".
"Of course he doesn't feel great". He said he was guilty of this situation and it's irresponsible.
"It was a very hard game for us because we made big mistakes around their goals".
"That's what we try".
Last season saw two titanic matches between the two - Tottenham destroyed Liverpool 4-1 at Wembley in October 2017, scoring three goals in the first half, and in the return fixture at Anfield it looked like Mo Salah had earned all three points for the Reds before an injury-time penalty from Harry Kane rescued a point for Spurs.
Tottenham goalkeeper Hugo Lloris will be out for "several weeks" with a thigh injury, but will retain the captaincy after his drink-drive conviction.
Spurs will have Heung-min Son available after his lengthy stint on worldwide duty with South Korea.