Tonight's match is part of celebrations to mark 100 years since the birth of anti-apartheid icon Nelson Mandela.
The forward had a stellar career at Athletic Bilbao, but never quite cut it in three seasons with Barca, largely hindered by the emergence of Messi.
"It is a pleasure to be in South Africa and I believe this huge crowd thoroughly enjoyed what both sides produced".
There also are fringe players in the squad such as Ousmane Dembele, and Lucas Digne, whom Sundowns reported was briefly held at the South African airport owing to a fever.
Mamelodi Sundowns coach Pitso Mosimane said: "If you look at the match and if you look at the result, you look at the goals you understand that this team [Barca] scores goals, they scored four goals yesterday".
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Earlier, South Africa pacer Dale Steyn also questioned the omission of national teammate David Miller from Punjab's playing XI. He first pulled him for a boundary before reverse-scooping a couple over the keeper's head to reduce the margin to 23 from 12.
"I just want to thank God for the opportunity to be able to play against the best footballers in the world". I would like to thank the president [Patrice Motsepe] for making it happen.
After the match, Barcelona flew out of the country immediately to continue with preparations for their last La Liga match of the season against Real Sociedad on Sunday at the Camp Nou.
The Spanish champions then doubled their lead in the 20th minute when Denis Suarez fed his namesake, Luis Suarez, who made no mistake when one-on-one with Denis Onyango.
Between the goals, Sundowns' star attacker Percy Tau had two chances, but his chip was saved by Marc-Andre ter Stegen and he fired a close-range free-kick over.
However, Barcelona were still finding holes in the Premieship champions' defence at will and Kekana had to clear a Dembele effort off his own line, while Denis Suarez almost added a third when his header hit the bar six minutes before half-time in Soweto.